The highest scoring word in Words With Friends is RAPPORT with a total of 13 points.
Synonyms: affinity, close/special relationship, (mutual) understanding, bond, empathy, harmony, sympathy, link, accord, relate to, get on (well) with, respond to, sympathize with, feel sympathy with, feel for, identify with, empathize with, connect with, understand, speak the same language as, be in tune with, be on the same wavelength as